|
|
4-hydroxyphenylacetate + O2 + NADPH + H+ <=> homogentisate + H2O + NADP+
|
1.14.13.18
4-hydroxyphenylacetate 1-monooxygenase
|
–
|
K
|
| |
BRENDA:
BR33652
KEGG:
R02516
MetaCyc:
1.14.13.18-RXN
|
|
|
|
4-hydroxyphenylacetate + O2 + NADH + H+ <=> homogentisate + H2O + NAD+
|
1.14.13.18
4-hydroxyphenylacetate 1-monooxygenase
|
–
|
K
|
| |
BRENDA:
BR33652-a
KEGG:
R02514
MetaCyc:
1.14.13.18-RXN_WOP
|
|
|
|
4-hydroxyphenylpyruvate + O2 <=> CO2 + homogentisate
|
1.13.11.27
4-hydroxyphenylpyruvate dioxygenase
|
–
|
BMK
|
| |
BRENDA:
BR37066
KEGG:
R02521
MetaCyc:
4-HYDROXYPHENYLPYRUVATE-DIOXYGENASE-RXN
SABIO-RK:
2446
|
|
|
|
O2 + homogentisate <=> H+ + 4-Maleylacetoacetate
|
1.13.11.5
homogentisate 1,2-dioxygenase
|
–
|
BMK
|
| |
BRENDA:
BR40469
KEGG:
R02519
MetaCyc:
HOMOGENTISATE-12-DIOXYGENASE-RXN
SABIO-RK:
2444
|
|
|
|
phytyl_diphosphate + homogentisate + H+ <=> 2-methyl-6-phytylbenzene-1,4-diol + CO2 + diphosphate
|
2.5.1.115
homogentisate phytyltransferase
|
–
|
MK
|
| |
BRENDA:
BR50958
KEGG:
R07500
MetaCyc:
RXN-2541
|
|
|
|
geranylgeranyl_diphosphate + homogentisate + H+ <=> diphosphate + 6-geranylgeranyl-2-methylbenzene-1,4-diol + CO2
|
2.5.1.115
homogentisate phytyltransferase
2.5.1.116
homogentisate geranylgeranyltransferase
|
–
–
|
BMK
|
| |
BRENDA:
BR50959
KEGG:
R10708
MetaCyc:
RXN-14929
|
|
|
|
nonaprenyl_diphosphate + homogentisate + H+ <=> 2-methyl-6-all-trans-nonaprenylbenzene-1,4-diol + CO2 + diphosphate
|
2.5.1.117
homogentisate solanesyltransferase
|
–
|
MK
|
| |
BRENDA:
BR50960
KEGG:
R08782
MetaCyc:
RXN-2761
|
|
|
|
3-hydroxyphenylacetate + NADPH + O2 + H+ <=> homogentisate + NADP+ + H2O
|
1.14.13.63
3-hydroxyphenylacetate 6-hydroxylase
|
–
|
K
|
| |
BRENDA:
BR661
KEGG:
R02517
MetaCyc:
1.14.13.63-RXN
|
|
|
|
3-hydroxyphenylacetate + NADH + O2 + H+ <=> homogentisate + NAD+ + H2O
|
1.14.13.63
3-hydroxyphenylacetate 6-hydroxylase
|
–
|
|
| |
BRENDA:
BR661-a
KEGG:
R02515
MetaCyc:
1.14.13.63-RXN_WOP
|
|
|
|
2-hydroxyphenylacetate + NADH + O2 <=> homogentisate + NAD+ + H2O
|
1.14.13
1.14.13.63
3-hydroxyphenylacetate 6-hydroxylase
|
–
–
|
K
|
| |
BRENDA:
BS386058-a
KEGG:
R05450
|
|
|
|
homogentisate + O2 + NADPH <=> 2,5-dihydroxybenzaldehyde + CO2 + NADP+ + H+ + H2O
|
4.1.1
|
–
|
K
|
| |
KEGG:
R02518
|
|
|
|
homogentisate + O2 <=> 2,5-dihydroxybenzaldehyde + CO2 + H2O
|
1.13.12
|
–
|
K
|
| |
KEGG:
R02520
|
|
|
|
2-hydroxyphenylacetate + reduced_[NADPH-hemoprotein_reductase] + O2 <=> homogentisate + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14
|
–
|
|
| |
MetaCyc:
RXN-18767
|
|
|
|
homogentisate + O2 <=> 4-Fumarylacetoacetate
|
1.13.11.5
homogentisate 1,2-dioxygenase
|
–
|
|
| |
BRENDA:
BS288856
|
|
|
|
Homogentisic_acid_lactone + H2O <=> homogentisate
|
3.1.1.25
1,4-lactonase
3.1.1.35
dihydrocoumarin hydrolase
|
–
–
|
|
| |
BRENDA:
BS382035
|
|
|
|
geranyl_diphosphate + homogentisate <=> diphosphate + (3-geranyl-2,5-dihydroxyphenyl)acetate
|
2.5.1.117
homogentisate solanesyltransferase
|
–
|
|
| |
BRENDA:
BS428636
|
|
|
|
4-hydroxyphenylpyruvate + O2 <=> homogentisate + CO2 + 4-hydroxyphenylacetate
|
1.13.11.27
4-hydroxyphenylpyruvate dioxygenase
|
–
|
|
| |
BRENDA:
BS424581
|
|
|
|
geranylgeranyl_diphosphate + homogentisate <=> diphosphate + (3-geranylgeranyl-2,5-dihydroxyphenyl)acetate
|
2.5.1.117
homogentisate solanesyltransferase
|
–
|
|
| |
BRENDA:
BS428639
|
|
|
|
2-hydroxyphenylacetate + NADPH + O2 <=> homogentisate + NADP+ + H2O
|
1.14.13.63
3-hydroxyphenylacetate 6-hydroxylase
|
–
|
|
| |
BRENDA:
BS386058
|
|
|
|
(2E,6E)-farnesyl_diphosphate + homogentisate <=> diphosphate + (3-(2E,6E)-farnesyl-2,5-dihydroxyphenyl)acetate
|
2.5.1.117
homogentisate solanesyltransferase
|
–
|
|
| |
BRENDA:
BS427748
|
|
